^29Si,^27Al Magic—Angle—Spinning Nuclear Magnetic Resonance（MAS NMR） Studies of Kaolinite and Its Thermal Transformation Products     

He Hongping  Hu Cheng  Guo Jiugao  Zhang Huifen 《中国地球化学学报》1995,14(1):78-82

²⁷Al,²⁹Si MAS NMR studies of kaolinite and its thermal transformation products show that in the kaolinite-mullite reaction series there is an extensive segregation of Al₂O₃ and SiO₂ and the reaction of Al₂O₃ with SiO₂ to form mullite is the main path of mullite formation. At about 850° C, the peak intensity of A1(V) reaches its maximum and with the further rise of temperature the A1(V) signal completely disappears. At about 950°C, γ-Al₂O₃ accounts for about 71% of the material phases containing Al atoms. In the series there is no obvious presence of Al-Si spinel. The²⁷Al and²⁹Si MAS NMR spectra show that there is an obvious difference between the temperature points for Al-O₂(OH)₄ octahedral sheet collapsing and Si-O₄ tetrahedral sheet breaking down.  相似文献   

Formation of Colloidal Silica and Alumina During Experimental Granodiorite Weathering     

Jiří Faimon 《Aquatic Geochemistry》2003,9(4):305-341

The role of aluminum and silica in the formation of colloids during granodiorite weathering was studied on the basis of long-term experiments in batch reactors. Rock samples were dissolved in un-buffered solutions of initial pH 3.2, 5.4, and 9.9 at ambient conditions for 500 days. During weathering, extremely high supersaturation with respect to various secondary solids was attained in the solutions. Consequently, new solids, part of which was conserved in solutions as colloids, condensed. The mean concentrations of colloidal Si reached values of 70, 50, and 48 mol 1^–1 in the alkaline, neutral, and acid solutions, respectively. The mean concentrations of colloidal Al, reached values of 34, 22, and 12 mol 1^–1 in the alkaline, neutral, and acid solutions, respectively. The concentration of colloids gradually decreased after 200-400 days of experiment. This phenomenon was interpreted as being due to the competition between homogeneous nucleation and crystal growth. At the initial stages of the experiments, the colloidal species (predominantly colloidal Al) comprised a large proportion of the total amounts of aqueous species. Their share, however, decreased with time. The molar Al/Si-ratios of colloids were as high as 2–2.5 at the early stages of the experiment. After 250–300 days of experiments, on the other hand, these ratios decreased to values of about 0.5 in both the neutral and alkaline solutions and to a value of 0.15 in the acid solution. The evolution of colloids was consistent with the evolution of secondary solids in the sequence Al-hydroxides – clay minerals (illite, chlorite), in both the neutral and alkaline solutions. In acid solutions, the evolution of Al/Si-colloids was influenced by the presence of sulfate ion and Al-sulfate precipitation. Besides Al and Si, other elements, in particular Ca or Mg as a major component and Na, K, P, S, and Cl as minor components, readily participated in the formation of colloids.  相似文献   

微硅粉(纳米硅)水泥注浆技术在地质灾害防治中的应用          下载免费PDF全文

杜嘉鸿  陈兰云  王杰  王述红 《探矿工程》2005,32(1):35-38

介绍了微硅粉(纳米硅)浆材的基本性能，应用微硅粉浆材处理基础的不均匀沉降等地质灾害，解决了工程实际问题。  相似文献   

Availability of Bauxite Reserves     

Meyer  F. M. 《Natural Resources Research》2004,13(3):161-172

Based upon a large database, this paper analyzes the record of bauxite mine production, exploration success, and resource depletion and evaluates the availability of bauxite reserves in the near future. The record clearly shows that for the past 50 years world bauxite production rose by an annual increase of over 5% while per capita consumption rose during the same period by about 4%. Time trends of the world bauxite reserve life index (RLI); that is, known world reserves of a given year divided by world production of the same year, are episodic and seem to follow bauxite price cycles. The present-day RLI indicates adequate bauxite supply for about 180 years and is the same as it was in 1950. However, if an annual growth rate of 5% is considered, the currently known reserves will be exhausted within the next 20 years and the reserve base will be adequate for not more than 25 years. This scenario is based, of course, on the unrealistic assumption that future exploration efforts fail to discover additional reserves. Evaluation of the quality, in terms of bauxite signatures, and quantity of presently known bauxite prospects that may be mined in future suggests that there is sufficient potential for adequate bauxite supply for the next 20 to 25 years at least. Bauxite signatures cover a wide range of values that allows selection of the most favorable bauxite prospects for future mining, both in economic as well as environmental terms. Although, there is the general believe that the world abundance of bauxite resources will ensure sufficient supply to meet future demands significant additional reserves have to be discovered if exponential growth rates continue. As the question of future bauxite supply is subject to economic and geologic principles one has to take into consideration that increasing exploration maturity in many mineral provinces will make it difficult to locate additional bauxite reserves and that decreasing real commodity prices will influence the level of investment in bauxite exploration.  相似文献   

Diatom Paleolimnological Record of Holocene Climatic and Environmental Change in the Altai Mountains, Siberia     

Karlyn S. Westover  Sherilyn C. Fritz  Tatyana A. Blyakharchuk  Herbert E. Wright 《Journal of Paleolimnology》2006,35(3):519-541

The sedimentary diatom records of three shallow lakes in the Altai Mountains, southern Siberia, were examined to assess the nature and timing of Holocene environmental changes. Few paleoenvironmental records, especially reconstructions not based on pollen, have been reported from this region. The lakes differ in elevation, annual precipitation, and catchment vegetation. Diatom assemblages in all lakes were dominated for the entire period of record by small benthic species of Pseudostaurosira Williams & Round, Staurosira Ehrenberg, and Staurosirella Williams & Round. Planktonic taxa only occur in very low abundances (<5%). The most diverse diatom flora was found in Dzhangyskol, which is situated at the lowest elevation within a forested catchment. A lack of detailed information on the ecological preferences of the dominant taxa and the complexity of environmental drivers make direct interpretation of the diatom record difficult. However, other proxies suggest that dramatic shifts in dominance between Staurosira elliptica and Staurosirella pinnata in Grusha Ozero reflect millennial-scale variability in climate. Together, chironomids and diatoms provide evidence of a cooling possibly correlative to the Younger Dryas Stade and subsequent early-Holocene warming consistent with pollen evidence of afforestation, which also is likely linked to increased humidity. By ~6000 cal year BP, the transition to a cooler, more continental climate had begun. The diatom record of Akkol shows significantly less variation in diatom community composition, but biogenic silica accumulation rates, a proxy for diatom productivity, appear to reflect climatic variability driven by insolation trends over the past 8000 years. Long-term variability in Dzhangyskol is not clearly linked to climate.  相似文献   

Methodologies for amorphous silica analysis   总被引：1，自引：0，他引：1  

L. Saccone  D.J. Conley  D. Sauer   《Journal of Geochemical Exploration》2006,88(1-3):235

Different methodologies have been investigated for their ability to extract amorphous silica (ASi) from soils and plant phytoliths. Methodologies typically used in soil science, including oxalate, acetate and citric extractions, were used in addition to an alkaline digestion technique commonly used in the aquatic sciences. Initial results show that the alkaline technique extracts nearly an order of magnitude greater amount of ASi. The alkaline extraction technique was tested on soil samples with and without acid and peroxide pre-cleaning. Samples, which were not pre-cleaned, showed a poor extraction efficiency of amorphous silica and poor reproducibility, while cleaned soil samples gave better reproducibility and an increase in the amount of Si extracted.  相似文献   

Technical Note Reactive silica and strength of fly ashes     

P.V. Sivapullaiah  J.P. Prashanth  A. Sridharan  B.V. Narayana 《Geotechnical and Geological Engineering》1998,16(3):239-250

The use of fly ash in geotechnical engineering depends greatly on its pozzolanic reactivity. Though many factors influence the reactivity of fly ash it is well recognized that reactive silica and lime content play a major role. A new, accurate and reliable method for the determination of reactive silica content of fly ash has been established. The reactive silica content, obtained as acid soluble silica in about 2 to 3 N hydrochloric acid, is found to correlate well with unconfined compressive strength of fly ashes. The reactive silica content of fly ash is also important in the stabilization of soils using fly ash. © Rapid Science Ltd. 1998  相似文献   

二氧化硅溶解度方程和地温计   总被引：8，自引：0，他引：8  

张生  李统锦 《地质科技情报》1997,16(1):53-58

对地表至下地壳和上地幔温压条件下二氧化硅溶解度实验研究的进展进行了综述，并给出了石英和非晶质ＳｉＯ２在纯水和盐水溶液中的溶解度定量方程，介绍了估算地热库温度的ＳｉＯ２地质温度计。  相似文献   

Time dependence of organic matter decay and mixing processes in Framvaren, a permanently anoxic fjord in South Norway     

David W. Dyrssen  Per O. J. Hall  Conny Haraldsson  Melissa Chierici  Jens M. Skei  H. Göte östlund 《Aquatic Geochemistry》1996,2(2):111-129

Three different layers have been identified in Framvaren, which has a maximum water depth of 184 m. One oxic layer above the redoxcline at 18–20 m. One anoxic layer from 20 to 100 m which is occasionally ventilated by a flow over the sill (which has a depth of 2.5 m), and finally a stagnant layer below 100 m. Using the release rate of silica from the bottom and measurements of the concentration of HTO it is possible to make some calculations on the annual volume of interleaving in the layers 25–50 m, 50–75 m, and 75–100 m together with the advective flows. Reliable values of the sulfide concentration were obtained by precipitating and weighing HgS together with careful protection of all anoxic water samples with argon. The light yellow color of the precipitate in the depth range 25 to 80 m indicates that the occasional ventilation will cause such reactions as 0.50₂ + H₂S S(colloidal) + H₂O. The elemental sulfur, being stabilized with HS^–, is set free upon the precipitation of HgS. The new data for the concentration of sulfide give an acceptable stoichiometry for the decay reaction of organic matter. This is not the case with the data of Yao and Millero. The mean values for the concentrations of ammonium and phosphate agree with the new data of Yao and Millero. The mol/mol C/N ratio of 10.1 found in trapped material by Naess and coworkers (1988) agrees with the stoichiometry of the dissolved constituents, i.e. C/N = 9.92 ± 0.45. A denitrification reaction is suggested to explain the high values of C/N. The vertical diffusion coefficient at 100 m calculated from the depth profile of silica was 0.92 × 10^–6 m² s^–1 which lies in the range of values given by Fröyland. Finally, the ¹⁴C age of the total dissolved inorganic carbon (Ct) in the water below 90 m was about 1600 years indicating a bioproduction in the period 8000 years B.P. to A.D. 1853 when a channel was opened between the fjord outside (Helvikfjord) and Framvaren.  相似文献   

Chemistry of high mountain lakes in siliceous chatchments of the Central Eastern Alps     

Roland Psenner 《Aquatic Sciences - Research Across Boundaries》1989,51(2):108-128

Alpine lakes in siliceous catchments of Tyrol and Carinthia (Austria) show signs of acidification. About 9% of the studied lakes have no alkalinity, more than 20% are below pH 6. About two thirds of all lakes have acid neutralizing capacities below 100 eq 1^–1. In spite of moderate precipitation acidity, some lakes show considerable concentrations of dissolved reactive aluminum during or shortly after snowmelt. High altitude lakes of the Alps are definitely more acidic than high mountain lakes in remote areas. Large differences in water and soil chemistry of nearby situated lakes were attributed to heterogeneities of bedrock geology. Paleolimnological investigations on former pH values of five lakes, based on diatom assemblages in the sediment, showed different developments: recent and past acidification, stable conditions, and alkalinization.  相似文献